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This unique book investigates the synthesis, kinetics, and thermal decomposition properties and processing of energy-producing materials used in propellants, explosives, pyrotechnic, and gas-generating compositions.
Thermal Decomposition and Combustion of Explosives and Propellants provides several mechanisms and stages for the thermal decomposition and combustion reactions of most flammable compounds and their mixtures, such asaliphatic and aromatic nitrocompounds, nitramines, nitroesters, organic azides, furazanes, tetrazols, difluoroamines, polynitrous heterocycles, and onium salts. The authors examine the classic problem of the dependence of explosive activity on molecular structure, using applications to predict the stability, compatibility, and the stabilization of explosives and propellant components. They also offer experimental results examining factors such as subsurface decomposition, evaporation, and dispersion of materials, which can be used to control combustion of condensed systems.
Providing several approaches to stability, safety, and controlled combustion of flammable substances, Thermal Decomposition and Combustion of Explosives and Propellants is a multi-dimensional resource for graduate students, researchers and professionals interested in chemical kinetics, the combustion and synthesis of high-energy materials, criminal forensics, and the field of explosives, powders, and solid rocket propellants.
G.B. Manelis
Introduction. Kinetic Problems of Decomposition of Explosives and Propellants. General Regularities of Thermal Decomposition of High-Energy Compounds. Aliphatic Nitrocompounds. Aromatic Nitrocompounds. Secondary Nitroamines. Organic Azides. Organic Difluoroamino Compounds. Heterocyclic Compounds. Nitroesters. Compounds with Mixed Functions. General Regularities of Thermal Decomposition of Onium Salts, Nitric and Perchloric Acids, Dinitramide. Ammonium Nitrate. Ammonium Perchlorate. Ammonium Dintramide. The Salts of Hydrazinium, Hydroxylammonium, and Nitronium. Metal Perchlorates and Nitrates, Metal Salts of Dinitramide. Basic Aspects of the Combustion Mechanism. Combustion of Pure Substances: Reactions in the Condensed Phase. Combustion of Pure Substances: Reactions in the Gas Phase. Combustion of Pure Substances: Reactions in the Condensed and Gas Phases. Combustion of Condensed Composite Systems.
