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Homogeneous Hydrogenation and Metathesis Reactions, a volume in the Advances in Catalysis series, covers hydrogenation and metathesis reactions in two separate sections. The first section is devoted to homogeneous hydrogenation reactions and related processes, including hydrogenation of alkenes, esters, olefins, etc. In the second section, the metathesis reactions of olefins, alkenes, and alkynes are presented. In addition, the industrial application of homogeneous metathesis reactions is investigated.- Includes thermodynamic and kinetic studies of homogeneous catalysts- Describes transition metal, ligand, and solvent role in homogeneous catalysts- Explains preparation, characterization, deactivation, and regeneration of homogeneous catalysts- Presents homogeneous catalysts by clusters, carbenes, fixed metal-complexes, and liquid-liquid multiphase catalysts
Section I: Hydrogenation Reactions with Homogeneous Catalysts1. A General Overview on Hydrogenation Catalytic Systems2. Mechanism and Stereochemistry of Hydrogenation Reaction3. Homogeneous Catalytic Hydrogenation of Alkenes, Alkynes, Allenes, Dienes, and Arenes4. Hydrogenation of Esters with Homogeneous Catalysts5. Homogeneous Hydrogenation of Olefins6. Hydrogenation of Ketones by Homogeneous Catalysts7. Homogeneous Hydrogenation of Imines8. Homogeneous Hydrogenation of Aromatics and Heteroaromatics9. Supported Hydrogenation Homogeneous Catalysts10. Homogeneous Hydrogenation of Benzene to Cyclohexane11. Homogeneous Transfer Hydrogenation Catalysed by Metal Complexes12. Homogeneous Hydrogenation in Aqueous Systems13. Chemical Reactor Design for Homogeneous Hydrogenation Processes14. Environmental Impacts and Economic Assessment of Homogeneous Hydrogenation ProcessesSection II: Metathesis Reactions with Homogeneous Catalysts15. An Introduction to Homogeneous Metathesis Catalysis16. Rhenium As a Homogeneous Metathesis Catalyst17. Olefin Metathesis Homogeneous Catalysts18. Homogeneous Catalysts for Alkene Metathesis19. Alkyne Metathesis Homogeneous Catalysis20. Industrial Applications of Homogeneous Metathesis Reactions