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The growth in the world's nuclear industry has resulted in a heightened focus on the need for next-generation nuclear fuel-cycle technologies. This volume provides a comprehensive look at the state of the science underlying solvent extraction in its role as the most powerful separation technique for the reprocessing of commercial spent nuclear fuel. The book explores selective extractions, third-phase formation, the effects of intense radiation upon the solvent, analytical techniques to measure process concentrations, new types of centrifugal contactors, and new chemistry that may offer the potential for further advances in the future.
Bruce Moyer has 30 years of experience in research and development on solvent extraction and ion exchange, focusing on radionuclide separations for environmental and waste cleanup, nuclear fuel cycles, and national-security applications in the USDOE complex. Dr. Moyer leads the Chemical Separations Group of ORNL's Chemical Science Division. He is the Editor of the journal Solvent Extraction and Ion Exchange.
Overview of Solvent Extraction Chemistry for Reprocessing. New Developments in Thorium, Uranium, and Plutonium Extraction. Overview of Recent Advances in An(III)/Ln(III) Separation by Solvent Extraction. Extraction of Radioactive Elements by Calixarenes. Quantitative Structure-Property Relationships in Solvent Extraction and Complexation of Metals. Simultaneous Removal of Radionuclides by Extractant Mixtures. Third-phase Formation in Liquid/Liquid Extraction: A Colloidal Approach. Radiolysis of Solvents Used in Nuclear Fuel Reprocessing. Automation of Extraction Chromatographic and Ion Exchange Separations for Radiochemical Analysis and Monitoring. Design Principles and Applications of Centrifugal Contactors for Solvent Extraction. Neoteric Solvents as the Basis of Alternative Approaches to the Separation of Actinides and Fission Products. Index.
