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This monograph deals with the novel concept of chemical physics concerning polymer non-crystalline phase. In the phase supramolecular model created, a small share of polymeric chains of bulky non-crystalline polymers is assembled in paracrystalline domains, which form continuous cellular carcass. Inside the carcass cells, polymeric chains form nanoporous spongy micelles. The functions of the micelles regarding their physical interactions with low molecular compounds and their behavior in chemical chain reactions are described. This monograph is of value and interest to students, postgraduates and scientists searching for new properties of polymers for applied purposes.
Yuri Arsenovich Mikheev, Gennady Zaikov, N.M Emanuel Institute of Biochemical Physics, Moscow, Russia.
PREFACE CHAPTER I. INTRODUCTION. THE PROBLEM OF STRUCTURAL-PHYSICAL ORGANIZATION OF POLYMERIC NON-CRYSTALLINE PHASE CHAPTER2. STRUCTURAL MODEL OF NON-CRYSTALLINE POLYMERIC MATRIX CHAPTER 3. SUPRAMOLECULAR ASPECTS OF NCPM CHEMICAL PHYSICS CHAPTER 4. KINETIC PROBING OF NCPM GLASSY-LIKE POLYMERS WITH THE HELP OF DIBENZOYL PEROXIDE CHAPTER 5. KINETIC MODEL OF DIBENZOYL PEROXIDE CHAIN REACTION WITH STERICALLY HINDERED PHENOLS CHAPTER 6. DIBENWYL PEROXIDE KINETIC PROBING OF MELT AND RUBBERY POLYMERS CHAPTER 7. THE EXAMPLES OF HETERO-NANOPHASE KINETIC DESCRIPTION OF PHOTOCHEMICAL REACTIONS